Resin systems cured with blocked acid catalysts

ABSTRACT

Resin systems cured with blocked acid catalysts formed by reaction of sulfonic acids with glycidamides. The blocked acids are used as catalysts and provide viscosity stability and pot life without significant decrease in catalytic activity in comparison with the corresponding free sulfonic acids.

This invention relates to acid curing resin systems and more particularly to acid curing resin systems containing blocked sulfonic acid catalysts.

Blocked acid catalysts are used in acid curing resin systems such as amino resins, melamine resins, urea-formaldehyde resins, phenol-formaldehyde resins and mixtures of such resins with alkyd, polyester or acrylic resins. Further acid-curable resins are methylol compounds, methylol ethers of polycarboxylic acid imides, for example derivatives of polyacrylic or methacrylic acid, urethane alkyds and resins containing carboxylic acid esters of N-methylolimides. The acid curing catalysts used are mainly organic acids including, for example, sulfonic acids. Since these acids result in a fairly rapid curing at temperatures as low as room temperature, they are not added to the resin until shortly before the application of the latter. In order, therefore, to make one-component systems possible, the use of masked or blocked curing catalysts from which the acid is released at elevated temperature, has already been suggested. Examples of these are amine salts of aromatic sulfonic acids, such as dimethyloxazolidine salts. These have the disadvantage that they result in a slow curing during storage to an unacceptable degree. In addition, problems of odor arise with these products. Also, resins cured with such blocked catalysts are found to be deficient in humidity resistance. Other examples of blocked catalysts are sulfonic acid adducts of conventional epoxy resins such as the glycidyl ethers of bisphenols and oligomers of such glycidyl ethers suggested in U.S. Pat. No. 4,192,826. These have the disadvantage that they require high temperatures for unblocking of the acid with the result that when they are used to cure resin systems at concentrations which do not cause excessive decrease in humidity resistance of the resin systems, they do not provide adequate cure at conventional baking temperatures.

According to the present invention, there is provided acid curing resin systems containing a blocked sulfonic acid catalyst. The blocked catalysts comprise the reaction product of a sulfonic acid and a glycidamide. Such products advantageously comprise at least one group per molecule represented by the formula: ##STR1##

Any sulfonic acid containing up to four sulfonic acid units per molecule may be used to form the present composition. Representative sulfonic acids are compounds of the formula: ##STR2## in which n is in the range of 1 to 4, and if n is 1, R₁ is for example C₁ to C₁₈ alkyl, phenyl which is unsubstituted or substituted for example with halogen, C₁ -C₁₂ alkyl, C₁ -C₄ alkoxy, C₁ -C₄ alkyl CONH, phenyl--CONH, --NO₂ or benzoyl, naphthyl which is unsubstituted or substituted for example with halogen, C₁ -C₁₂ alkyl or C₁ -C₄ alkoxy, C₅ -C₆ cycloalkyl, C₇ C₉ aralkyl, camphoryl, --CF₃, --CCl₃, --F or NH₂, and if n=2, R₁ is for example --CH₂ --_(m) where m is 2 to 8, or R₁ is for example phenylene or naphthylene which are unsubstituted or substituted for example with C₁ -C₁₂ alkyl, and if n=3, R₁ is for example a trivalent aliphatic radical (C.sub. p H_(2p-1)) where p is 2 to 8, or R₁ is for example a trivalent C₆ -C₁₀ aromatic radical which is unsubstituted or substituted for example with C₁ -C₁₂ alkyl, and if n=4, R₁ is for example a tetravalent aliphatic radical (C_(p) H_(2p-2)) where p is 2 to 8, or R₄ is for example a tetravalent C₆ -C₁₀ aromatic radical which is unsubstituted or substituted for example with C₁ -C₁₂ alkyl.

Preferred sulfonic acids are aromatic sulfonic acids and include benzene sulfonic acid, benzenedisulfonic acid, o- and p- toluenesulfonic acid, toluene disulfonic acid, C₂ -C₁₈ alkylbenzenesulfonic acids, C₂ -C₁₈ alkylbenzenedisulfonic acids, o- and p-dodecylbenzene-sulfonic acid, naphthylenesulfonic acid, and C₁ -C₁₈ alkylnaphthalene sulfonic acids naphthalenedisulfonic acid and C₁ -C₁₈ alkylnaphthalenedisulfonic acids.

Any glycidamide containing up to four glycidamide groups per molecule can be reacted with the sulfonic acid to form the blocked acids of the present invention. Reaction ratios are preferably selected to limit the number of blocked acid units to an average of 6 per molecule of blocked acid catalyst. When the valence of the sulfonic acid is greater than one, a monoglycidamide is preferably used as the blocking agent. Similarly when the glycidamide contains more than one glycidamide group per molecule, a monovalent sulfonic acid is preferably selected for reaction. Representative glycidamides include for example glycidamide, N-alkylglycidamides in which alkyl is C₁ -C₁₂, N-arylglycidamides in which aryl is C₆ -C₁₀, N-alkylene diglycidamides in which alkylene is C₁ -C₁₂, N-arylene diglycidamides in which arylene is C₆ -C₁₀, and mono- and poly-glycidamide derivatives of amino compounds such as urea, glycouril and aminotriazines for example melamine and benzoguanamine, in which the glycidamide is linked to the amino compound by a methylene group. Such glycidamidomethyl amino compounds include those disclosed in U.S. Pat. No. 4,582,894. They offer the opportunity for incorporation into resin system upon cure, not only through their epoxy groups but also through alkoxymethyl substituents of the amino compounds.

The blocked acid catalyst is prepared by mixing the two components together in bulk or in solution in proportions such that there is 0.1 to 1 sulfonic acid group per glycidamido group, and the resultant mixture is allowed to react for 20 to 60 minutes at a temperature in the range of 20 to 150° C., preferably 20 to 80° C. The order of addition of the reactants is immaterial; however it is preferred to add the sulfonic acid to the glycidamide at a temperature which maintains the reactants in liquid form.

The blocked acid catalyst can be used to catalyze the cure of any acid-curable resin system. For example it can be used to catalyze the cure of resins containing hydroxy, carboxy, or amide groups by amino resins such as amino triazine formaldehyde resins and urea-formaldehyde resins. Suitable amino resins are prepared for example by the condensation of at least one aldehyde with at least one of urea, N,N'-ethyleneurea, dicyandiamide, glycouril and aminotriazines such as melamines and guanamines such as guanamine and acylguanamines in which the aryl group contains from 2 to 7 carbon atoms, such as aceto and benzoguanamine. Among the aldehydes that are suitable are formaldehyde, revertable polymers thereof such as paraformaldehyde, acetaldehyde, crotonaldehyde, and acrolein. Preferred are formaldehyde and revertable polymers thereof. The amino-resins are preferably alkylated with at least one and up to six alkanol molecules containing 1 to 8 carbon atoms. The alkanols can be straight chain, branched or cyclic or mixtures thereof. Among preferred members of this class are the methylated malamine-formaldehyde resins such as hexamethoxymethylmelamine and mixed peralkoxy derivatives such as trimethoxymethyltributoxymethylmelamine. These crosslinking agents have substantially 100% nonvolatile content.

The amino resin crosslinking agent is present in an amount of 10-70 parts by weight of the curable resin system and preferably 20-50 parts.

The resin containing hydroxy, carboxy or primary or secondary amide groups curable by means of the amino resin may be a vinyl addition polymer formed by interpolymerization of acid, hydroxy, or amide monomer and non-functional vinyl monomers such as acrylic monomers, styrene monomers, vinyl esters and acrylonitriles and the like. The acid monomer may be selected from the group consisting of acrylic acid, methacrylic acid, crotonic acid, maleic acid, fumaric acid, itaconic acid and monohydrocarbyl esters of monounsaturated polyacids such as the alkyl hydrogen maleates and alkyl hydrogen fumarates for example methyl hydrogen maleate, butyl hydrogen maleate, octyl hydrogen fumarate and the like. The hydroxy monomer may be selected from the group consisting of hydroxyhydrocarbyl esters of monounsaturated mono- and poly-acids such as 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate, 2-hydroxypropyl acrylate, 3-hydroxypropyl methacrylate, bis(2-hydroxyethyl)maleate, bis(3-hydroxypropyl) fumarate and the like. The amide monomer may be selected from the group consisting of acrylamide, methacrylamide, and N-hydrocarbylacrylamides such as N-methacrylamide and N-ethylacrylamide and the like. Also the resin can be selected from conventional polyester, polyamide, polyether-urethane and polyester-urethane condensation products. The polyester condensation products include conventional oil-free and oil modified alkyd resins and oil-free and oil modified urethanealkyds. In general the condensation polymers possess a functionality of at least two provided by carboxy, and/or hydroxy, and/or primary or secondary amide. The resin can also be a polyhydric alcohol such as a styrene-allyl alcohol copolymer or a polyether polyol.

In general, the acid curable resin has a number average molecular weight of at least about 500 and is preferably in the range of about 1000 to 20000. The functionality of the resin is at least 2 and is generally present to provide from about 1 equivalent of functional group per 150 to 10000 units of molecular weight.

The blocked acid catalyst utilized in thermosetting compositions is present in sufficient amount to accelerate the cure of the compositions. A satisfactory amount is generally in the range of 0.001 to 0.02 equivalents of potentially available sulfonic acid when unblocking takes place per 100 parts of resin solids.

The compositions comprising reactive resin and amino crosslinking agent may also include solvents to provide a viscosity suitable for the method of application. Preferably the compositions contain no more than about 30 weight percent of solvent based on the weight of solvent and resins. The compositions may also include various conventional modifiers such as catalysts, accelerators, flow control agents, surface active agents, organic and inorganic pigments, inert fillers, inhibitors, stabilizers and plasticizers.

While solvent coating compositions have been selected as resin systems amenable to cure by means of the blocked acid catalysts of the present invention, other resin systems such as thermosetting molding compositions, laminating compositions, potting compounds and powder coating compositions can be cured by the blocked acid catalysts.

The following examples illustrate the invention but are not to be construed as limiting its scope. All quantities are on a weight basis unless otherwise indicated.

EXAMPLES 1-4 AND COMPARATIVE EXAMPLES 1-3

PREPARATION OF BLOCKED CATALYSTS

The blocked catalysts are prepared by mixing at room temperature (24-26° C.). The reaction that takes place between the acid and the blocking agent (either epoxy or amine) is mildly exothermic and proceeds quite readily.

EXAMPLE 1

p-Toluenesulfonic acid/Glycidamide

122.9 parts by weight of a 70% p-toluenesulfonic acid solution supplied in Methanol by Jim Walters Resources is mixed with 282.6 parts by weight of methanol. This solution is then added to 167.5 parts by weight of a 26% glycidamide solution in Dowanol PM to give a homogeneous clear solution.

EXAMPLE 2

p-Toluenesulfonic acid/Glycidamidomethyl melamine

246.0 parts by weight of the 70% p-toluenesulfonic acid solution of Example 1 is mixed with 100.0 grams of isopropanol. This solution is then added to 526.0 grams of a 60% solution in Dowanol PM of an epoxy product obtained by condensation of 1 mole of a methoxymethylmelamine sold by Monsanto under the tradename Resimene® R-755, 2.75 moles of acrylamide, and 1 mole of pentanol, followed by epoxidization under basic conditions, using potassium hydroxide and hydrogen peroxide in the presence of acetonitrile. The epoxide equivalent weight of the epoxy product is 270-330. The viscosity at 25° C. is 150-400 cps. The number average molecular weight is 1200. The color is 3 max. (Gardner) at 25° C.

EXAMPLE 3 Dodecylbenzenesulfonic acid/Glycidamide

233.0 parts by weight of a 70% dodecylbenzenesulfonic acid solution supplied in isopropanol by American Cyanamid is mixed with 415.0 parts by weight of methanol. This solution is then added to 167.5 parts by weight of a 26% glycidamide solution of Example 1 till homogeneous and clear.

EXAMPLE 4 Dodecylbenzenesulfonic acid/glycidamidomethyl melamine

233.0 parts by weight of the 70% dodecylbenzenesulfonic acid solution used in Example 2 is mixed with 319.0 parts by weight of additional isopropanol. This solution is then added to 263.0 grams of the epoxy product used in Example 3 and mixed until clear and homogeneous.

COMPARATIVE EXAMPLE 1

p-Toluenesulfonic acid/bisphenol A epoxy resin

110.0 parts by weight of the 70% p-toluenesulfonic acid used in Example 1 is mixed with 203.0 parts by weight of additional methanol. This solution is then added to 200.0 parts by weight of Epon 815 resin, an epoxy resin supplied by Shell as a 100% active liquid. These two components are then mixed till homogeneous and clear. Epon 815 is an epichlorohydrin/bisphenol A reaction product which contains a reactive diluent (glycidyl ether type). It is supplied by Shell Chemical Company as a 100% active liquid material. The epoxide equivalent is 175-195. The viscosity at 25° C. is 5-7 poise. The average molecular wieght is 330. The color is 5 max. (Gardner) at 25° C. COMPARATIVE EXAMPLE 2 Dodecylbenzenesulfonic acid/bisphenol A epoxy resin

210.0 parts by weight of the 70% dodecylbenzene sulfonic acid solution used in Example 3 is mixed with 325.0 parts by weight of additional methanol. This solution is then added to 200.0 parts by weight of Epon 815 resin. These two components are then mixed till homogeneous and clear.

COMPARATIVE EXAMPLE 3 Dodecylbenzenesulfonic acid/Dimethyloxazolidine (DMO)

204.0 parts by weight of the 70% dodecylbenzene sulfonic acid solution of Example 3 is mixed with 233.5 grams of additional Methanol. This solution is then added to 62.5 grams of a 78% dimethyloxazolidine solution in water, supplied by Angus Chemicals. These two components are then mixed till clear and homogeneous.

EXAMPLES 5-8 AND COMPARATIVE EXAMPLES 4-6

A Resin formulation was prepared by blending a 60 weight percent solution of a hydroxy functional acrylic resin of number average molecular weight 2000, weight average molecular weight 4000 and hydroxyl number 140 with a hexamethoxymethyl melamine resin sold by Monsanto Company under the registered trademark Resimene 755. The acrylic resin was a copolymer of hydromethyl acrylate, methyl acrylate, butyl acrylate and styrene. To individual samples of the blend, the blocked sulfonic acids of examples 1-4 were added. Resin blends containing sulfonic acid and blends containing acid catalysts blocked with conventional epoxy were also prepared for comparative tests. All p-toluenesulfonic acid systems provided 0.4 weight percent p-toluenesulfonic acid based on total resin present in the system and all dodecylbenzenesulfonic acid systems provided 0.8 weight percent acid when unblocking took place. The compositions of the blend samples are set forth in Table 1 and data for viscosity stability at 60° C. are set forth in Table 2 illustrating the fast gellation which occurs with unblocked catalyst (comparative examples 4,5) and the slow increase in viscosity with the blocked catalysts in which blocking is achieved by reaction with epoxy compounds.

                                      TABLE 1                                      __________________________________________________________________________     Resin Blends (parts by weight)                                                                    Comp.                                                                              Comp.                                                                              Comp.                                                                              Comp.                                                                              Comp.                                       Ex 5     Ex 6                                                                              Ex 7                                                                              Ex 8                                                                               Ex 4                                                                               Ex 5                                                                               Ex 6                                                                               Ex 7                                                                               Ex 8                                        __________________________________________________________________________     Acrylic                                                                              143                                                                               143                                                                               143                                                                               143 143 143 143 143 143                                         Resin                                                                          Resimene                                                                              53                                                                                53                                                                                53                                                                                53  53  53  53  53  53                                         755 Resin                                                                      pTSA  -- -- -- --  .78 --  --  --  --                                          DDBSA -- -- -- --  --  1.56                                                                               --  --  --                                          Catalyst                                                                             3.70                                                                              -- -- --  --  --  --  --  --                                          Ex 1                                                                           Catalyst                                                                             -- 2.75                                                                              -- --  --  --  --  --  --                                          Ex 2                                                                           Catalyst                                                                             -- -- 5.50                                                                              --  --  --  --  --  --                                          Ex 3                                                                           Catalyst                                                                             -- -- -- 5.50                                                                               --  --  --  --  --                                          Ex 4                                                                           Catalyst                                                                             -- -- -- --  --  --  3.70                                                                               --  --                                          Comp. Ex 1                                                                     Catalyst                                                                             -- -- -- --  --  --  --  5.50                                                                               --                                          Comp. Ex 2                                                                     No catalyst                                                                          -- -- -- --  --  --  --  --  --                                          Xylene                                                                               25 25 25 25  25  25  25  25  25                                          __________________________________________________________________________      pTSA = ptoluenesulfonic acid                                                   DDBSA = dodecylbenzenesulfonic acid                                      

                  TABLE 2                                                          ______________________________________                                         Viscosity Stability of Resin Blends at 60° C.                                  Viscosity, cps                                                                 Initial                                                                              1 week   2 weeks  3 weeks                                                                               4 weeks                                  ______________________________________                                         Example                                                                        5        70      290      1010   1710   gelled                                 6        70      280      900    1640   gelled                                 7        70      310      900    1540   4000                                   8        70      300      850    1520   3800                                   Comparative                                                                    Example                                                                        4        75      1920     gelled --     --                                     5        75      1250     gelled --     --                                     6        70      240      720    1250   3150                                   7        70      250      700    1200   3000                                   8        75       75       75     75     75                                    ______________________________________                                    

The resin blends were applied by drawdown to primed Bonderite 40 steel panels to provide a dry coating thickness of 1.5-2.0 mil (37-51 micron) and the coatings were cured for 30 minutes at 250° F. (121° C.) and tested for solvent resistance, pendulum hardness (Konig oscillator) and gloss retention (60° angle) under condensing humidity conditions at 100% relative humidity and at 38° C. for 240 hours and upon exposure under QUV conditions for 1000 hours under cycles of condensing humidity for 4 hours at 50° C. and UV exposure for 8 hours at 60° C. The data are presented in Table 3 and show that coatings cured with sulfonic acids blocked with glycidamides are equivalent in performance to coatings cured with free acid and are significantly superior to coatings cured with sulfonic acids blocked with conventional epoxy resins.

                  TABLE 3                                                          ______________________________________                                         Evaluation of Coating Prepared from Acid                                       Catalyzed Resin Blends                                                                Solvent  Pendulum  Condensing                                                  Resistance                                                                              Hardness  Humidity  QUV                                               (MEK double                                                                             (Konig    Gloss     Gloss                                             rubs)    oscill.)  Retention Retention                                  ______________________________________                                         Example                                                                        5        100+           111.8   91        86                                   6        100+           107.5   91        86                                   7        100+           109.9   90        85                                   8        100+           105     91        85                                   Comparative                                                                    Example                                                                        4        100+           112     91        86                                   5        100+           110     90        85                                   6        50     (break) 90.0    80  (sl w)                                                                               70  (sl y)                           7        45     (break) 89.1    81  (sl w)                                                                               70  (sl y)                           ______________________________________                                          w-whitening                                                                    yyellowing                                                               

EXAMPLE 9 and COMPARATIVE EXAMPLE 9-11

A series of resin formulations were prepared by blending with Resimene 755 melamine resin. To individual samples of the blend free dodecylbenzenesulfonic acid, and the blocked acids of example 4 and comparative examples 3 were added. The compositions of the blend samples are set forth in Table 4 and viscosity stability data in Table 5 showing the superior viscosity stability of the glycidamide blocked catalyst system.

                  TABLE 4                                                          ______________________________________                                         Resin Blends (parts by weight)                                                                   Comp.   Comp.      Comp.                                                Ex. 9  Ex. 9   Ex. 10     Ex. 11                                    ______________________________________                                         Acrylic resin                                                                               143      143     143      143                                     Resimene 755 Resin                                                                          53       53      53       53                                      DDBSA        --       1.56    --       --                                      Catalyst Ex. 4                                                                              5.50     --      --       --                                      Catalyst Comp. Ex. 3                                                                        --       --      3.82     --                                      No catalyst  --       --      --       --                                      Xylene       25       25      25       25                                      ______________________________________                                    

                  TABLE 5                                                          ______________________________________                                         Viscosity Stability of Resin Blends at 60° C.                                  viscosity, cps.                                                                initial                                                                              4 days  12 days 18 days                                                                              25 days                                                                              31 days                               ______________________________________                                         Example 9                                                                               190     750     1560  2640  5000  gelled                              Comp Ex 9                                                                               220     1212    gelled                                                                               --    --    --                                  Comp Ex 10                                                                              190     555     8600  gelled                                                                               --    --                                  Comp Ex 11                                                                              190     300      300   300   320  320                                 ______________________________________                                    

The resin blends were applied by drawdown to primed Bonderite 40 steel panels to provide a dry coating thickness of 1.5-2.0 mil (37-51 micron) and the coatings were cured under a range of conditions (30 minutes at 210° F., 250° F. and 275° F., -99° C., 121° C. and 135° C.) and tested for solvent resistance, pendil hardness, Tukon hardness and gloss retention (60° angle) after 240 hours under condensing humidity conditions at 100% relative humidity and 38° C. and gloss retention upon exposure under QUV conditions for 750 hours (cycle time 4 hours of condensing humidity at 50° C., 8 hours UV exposure at 65° C.) and adhesion rating after 1700 hours. The data are presented in Table 6. They show that the glycidamide blocked catalyst provides a faster cure rate than amide blocked catalyst and superior coating properties.

                                      TABLE 6                                      __________________________________________________________________________     Cure Response of Resin Blends                                                             Example 9    Comp. Example 9                                                                             Comp. Example 10                                                                            Comp. Example 11                        210° F.                                                                     250° F.                                                                      275° F.                                                                     210° F.                                                                     250° F.                                                                      275° F.                                                                     210° F.                                                                      250° F.                                                                     275° F.                                                                     210° F.                                                                      250°                                                                        275°         __________________________________________________________________________                                                                F.                  Solvent resistance,                                                                       64  100  100 100 100  100 42   100 100 sticky                                                                              sticky                                                                             sticky              MEK double rubs                                                                           (break)                                                                            (no  (no (mars                                                                              (no  (no (break)                                                                             (no (no (no  (no (no                                mar) mar)                                                                               badly)                                                                             mar) mar)     mar)                                                                               mar)                                                                               cure)                                                                               cure)                                                                              cure)               Pencil hardness                                                                           B   H-2H 2H  B   H-2H 2H  B    H-2H                                                                               H-2H                                                                               --   --  --                  Tukon hardness,                                                                           <1  9.1  10.3                                                                               <1  9.5  10.7                                                                               <1   8.9 10.1                                                                               --   --  --                  kg/mm.sup.2                                                                    Gloss retention,                                                                          85/80                                                                              86/85                                                                               85/84                                                                              83/82                                                                              85/85                                                                               86/83                                                                              83/71                                                                               84/83                                                                              84/83                                                                              --   --  --                  initial/final                        (blushed)                                 (condensing humidity)                                                          Gloss retention,                                                                          --  86/80                                                                               --  --  85/80                                                                               --  --   84/75                                                                              --  --   --  --                  initial/final                                                                  (QUV conditions)                                                               Adhesion rating                                                                           --  10   --  --  10   --  --   9   --  --   --  --                  after 1700 hours                                                               QUV exposure                                                                   Coating resistivity                                                                       --  0.75 --  --  1.0  --  --   0.6 --  --   --  --                  (initial) megaohms.                                                            __________________________________________________________________________ 

I claim:
 1. An acid curing resin system comprising an amino resin, a resin containing hydroxy, carboxy, primary amide or secondary amide groups and a sulfonic acid catalyst blocked by reaction with a glycidamide.
 2. The acid curing resin system of claim 1 wherein the blocked sulfonic acid comprises at least one unit per molecule represented by the formula: ##STR3##
 3. The acid curing resin system of claim 1 wherein the sulfonic acid comprises from 1 to 4 sulfonic acid groups per molecule.
 4. The acid curing resin system of claim 1 wherein the sulfonic acid is an aromatic sulfonic acid.
 5. The acid curing resin system of claim 4 wherein the sulfonic acid is selected from the group consisting of benzenesulfonic acid, alkylbenzenesulfonic acid, benzene disulfonic acid, alkylbenzene disulfonic acid, naphthalene sulfonic acid, alkylnaphthalenesulfonic acid, naphthalene disulfonic acid, and alkylnaphthalene disulfonic acid in which alkyl is C₁ to C₁₈.
 6. The acid curing resin system of claim 1 wherein the glycidamide is selected from the group consisting of glycidamide and N-substituted glycidamides comprising from 1 to 4 glycidamido groups per molecule.
 7. The acid curing resin system of claim 1 wherein the glycidamide is a glycidamidomethyl substituted amino resin.
 8. The acid curing resin system of claim 1 wherein the resin containing hydroxy, carboxy, primary amide or secondary amide groups is an alkyd, a polyester or an acrylic resin.
 9. The acid curing resin system of claim 8 wherein the amino resin is an alkylated condensation product of formaldehyde and an amino compound selected from urea, N, N'-ethyleneurea, dicyandiamide, glycouril, melamine, acetoguanamine and benzoguanamine.
 10. The acid curing resin system of claim 9 wherein the sulfonic acid is an aromatic sulfonic acid.
 11. The acid curing resin system of claim 10 wherein the sulfonic acid is selected from the group consisting of benzenesulfonic acid, alkylbenzenesulfonic acid, benzene disulfonic acid, alkylbenzene disulfonic acid, naphthalene sulfonic acid, alkylnaphthalenesulfonic acid, napthalene disulfonic acid, and alkylnaphthalene disulfonic acid in which alkyl is C₁ to C₁₈.
 12. The acid curing resin system of claim 11 wherein the glycidamide is selected from the group consisting of glycidamide and N-substituted glycidamides comprising from 1 to 4 glycidamido groups per molecule.
 13. The acid curing resin system of claim 11 wherein the glycidamide is a glycidamidomethyl substituted amino resin.
 14. The acid curing resin system of claim 13 wherein the alkyd, polyester of acrylic resin is a hydroxy resin of number average molecular weight in the range of 500 to 20000 and contains 1 hydroxy group per 150 to 10000 units of molecular weight. 